283. The oxidation of malonic acid by manganic sulphate
β Scribed by Kemp, T. J. ;Waters, William A.
- Book ID
- 120837458
- Publisher
- The Royal Society of Chemistry
- Year
- 1964
- Weight
- 396 KB
- Category
- Article
- ISSN
- 0368-1769
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π SIMILAR VOLUMES
## Abstract The kinetics of oxidation of diβproline by manganic sulphate in the acidic medium have been studied. The reaction is first order with respect to dlβproline and manganic sulphate and inverse first order with respect to hydrogen ions. A reaction mechanism has been proposed.
## Abstract The oxidation of malonic acid by ceric ions has been investigated in sulfuric acid solution under a variety of conditions. The initial rate at low ceric ion concentrations is first order in each of the two reactants and has an activation energy of 11.6 kcal/mol; the instantaneous rate c