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2,6,10-Tris(dialkylamino)trioxatriangulenium Ions. Synthesis, Structure, and Properties of Exceptionally Stable Carbenium Ions

✍ Scribed by Laursen, Bo W.; Krebs, Frederik C.; Nielsen, Merete F.; Bechgaard, Klaus; Christensen, Jørn B.; Harrit, Niels


Book ID
121199066
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
206 KB
Volume
120
Category
Article
ISSN
0002-7863

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Fifteen title compounds, e.g. (I)-(III), are prepared essentially as described previously. Evaluation of their absorption, emission and laser properties shows that N-allyl substituted derivatives (Ia) and (IIa) have high fluorescence quantum yields and laser efficiencies of 137 and 140%, respectivel