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2,6-Bis[(dimethylamino) methyl]phenylsodium: the first trimeric organosodium compound

โœ Scribed by Remco den Besten; Lambert Brandsma; Anthony L. Spek; Jan A. Kanters; Nora Veldman


Book ID
103232927
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
287 KB
Volume
498
Category
Article
ISSN
0022-328X

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The first rotational isomers of thiobenzaldehydes, TbtCH=S (2a and 2b: Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl), were synthesized and isolated as stable crystalline compounds by the desulfurization of the corresponding overcrowded cyclic polysulfides TbtCHS, (n = 5 or 8) with phosphine rea