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Synthesis and structure of a bis-ortho-chelated aryllithium compound: 2,3,5,6-tetrakis[(dimethylamino)methyl]phenyllithium dimer

โœ Scribed by Adolphus A. H. van der Zeijden; Gerard van Koten


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
297 KB
Volume
107
Category
Article
ISSN
0165-0513

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Synthesis of a polymetallic Pt, Sn compl
โœ Wagner M. Teles; Nivaldo L. Speziali; Carlos A.L. Filgueiras ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 142 KB

Reaction between 2,3,5,6-tetrakis(a-pyridyl)pyrazine (TPP) and the dimer , in which TPP behaves as a bis(bidentate) ligand between the two Pt atoms of the cation. Insertion of SnCl 2 into the Pt-Cl bonds of this compound led to an unusual rearranged product, (2), with a rare example of a pentacoor