2,6-Bis(4-methylphenyl)-1-nitroso-3,5-diphenyl-2,3,5,6-tetrahydropyridin-4(1H)-one
✍ Scribed by Suresh, J. ;Alex Raja, V. P. ;Perumal, S. ;Natarajan, S.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 351 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title molecule, C 31 H 28 N 2 O 2 , the piperidinone ring adopts the usual twist-boat conformation. The aryl rings at positions 2 and 3 are axial and those at positions 5 and 6 are equatorial. In the crystal structure, there are no hydrogen bonds nor are there any significant Á Á Á stacking interactions and, apart from two weak C-HÁ Á Á(arene) interactions, molecules are separated by normal van der Waals distances.
📜 SIMILAR VOLUMES
In the title compound, C 10 H 10 N 4 O, the tetrazine ring is twisted with respect to the benzene ring, with a dihedral angle of 14.8 (4) .
The title compound, C~9~H~9~ClN~4~, was prepared from sodium borohydride and 3-(4-chlorophenyl)-6-methyl-1,2,4,5-tetrazine. The molecule can be considered to be homoaromatic. The tetrazine ring adopts an unsymmetrical boat conformation.
## Abstract 2‐Pyridin‐3‐ylbenzoxazoles were synthesized by the reaction between 3‐pyridinecarboxaldehyde and substituted __o__‐aminophenols in the presence of iodobenzene diacetate. The resulting benzoxazoles 3 were treated with methyl iodide to give the corresponding pyridinium salts 4 which under