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3-(4-Chloro­phen­yl)-6-methyl-1,6-dihydro-1,2,4,5-tetra­zine

✍ Scribed by Xu, Feng ;Hu, Wei-Xiao ;Zhou, Wei ;Xia, Chun-Nian

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
268 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C~9~H~9~ClN~4~, was prepared from sodium borohydride and 3-(4-chlorophenyl)-6-methyl-1,2,4,5-tetrazine. The molecule can be considered to be homoaromatic. The tetrazine ring adopts an unsymmetrical boat conformation.

📜 SIMILAR VOLUMES

3,6-Bis(4-chloro­phen­yl)-1-isobutyr­yl-
3,6-Bis(4-chloro­phen­yl)-1-isobutyr­yl-1,4-dihydro-1,2,4,5-tetra­zine
✍ Rao, Guo-Wu ;Hu, Wei-Xiao 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 271 KB

The title compound, C 18 H 16 Cl 2 N 4 O, was prepared from isobutyric anhydride and 3,6-bis(4-chlorophenyl)-1,2dihydro-1,2,4,5-tetrazine. The central six-membered ring has a boat conformation.

3-(4-Methoxy­phen­yl)-6-methyl-1,2,4,5-t
3-(4-Methoxy­phen­yl)-6-methyl-1,2,4,5-tetra­zine
✍ Xu, Feng ;Hu, Wei-Xiao 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 105 KB

In the title compound, C 10 H 10 N 4 O, the tetrazine ring is twisted with respect to the benzene ring, with a dihedral angle of 14.8 (4) .

6-(4-Methoxy­phen­yl)-3-phenyl-1,2,4,5-t
6-(4-Methoxy­phen­yl)-3-phenyl-1,2,4,5-tetra­zine
✍ Xu, Feng ;Hu, Wei-Xiao 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 118 KB

In the title molecule, C 16 H 14 N 4 O, the tetrazine ring makes dihedral angles of 6.77 (12) and 70.5 (5) with the phenyl and methoxy-substituted benzene rings, respectively. The crystal packing exhibitsstacking interactions and weak intermolecular C-HÁ Á ÁN hydrogen bonds.