In the solid state, the title mononuclear octahedral rhodium(III) complex, [RhCl 3 (C 13 H 15 N 3 )]ÁH 2 O, shows a hydrogen bond between the equatorial Cl atom and the solvent water molecule.
[2,6-Bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine]trichlororhodium(III) dibenzene solvate
✍ Scribed by Cabort, Amel ;Therrien, Bruno ;Bernauer, Klaus ;Süss-Fink, Georg
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 135 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.055 wR factor = 0.165 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.031 wR factor = 0.080 Data-to-parameter ratio = 17.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The crystal structure of the title compound, C 21 H 18 N 2 O 5 , was determined in order to study the electrocyclic reactivity of 3,4diaryl-1H-pyrrole-2,5-dione derivatives. Intermolecular hydrogen bonds form sheets.