245. Acridine syntheses and reactions. Part V. A new dehalogenation of 5-chloroacridine and its derivatives
β Scribed by Albert, Adrien ;Royer, Richard
- Book ID
- 121201855
- Publisher
- The Royal Society of Chemistry
- Year
- 1949
- Weight
- 390 KB
- Category
- Article
- ISSN
- 0368-1769
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π SIMILAR VOLUMES
## Abstract BβChloroacridine (II) was converted to acridine in 80% yiold by hydrogenation in the presence of potassium hydroxide and ranoyβnicked catalyst at atmospheric picture followed by oxidation of the resulting acridnn (III) with chromic acid. The scope of the now reaction for the preparation
Hydrogenolysis of gmelinol 8 with sodium in liquid ammonia gives a triol 9, which is converted under various reaction conditions into a range of derivatives including the di-and tri-O-methyl ethers 10 and I1, a 3,4-dibenzyl-3-hydroxy-tetrahyckofuran 12, and its acetate 13. These derivatives undergo