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2,4-dimethyl-5-hexanolide, a trail pheromone component of the carpenter antcamponotus herculeanus

✍ Scribed by H. J. Bestmann, U. Haak, F. Kern, B. Hölldobler


Book ID
120794588
Publisher
Springer
Year
1995
Tongue
English
Weight
354 KB
Volume
82
Category
Article
ISSN
0028-1042

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Hydrogenation of 4-cholesten-3-one (1) with tritium gas over palladium black in pyridine afforded [P-4,5-SH]-cholestan-3-one (2a). Tritium NMR showed that there was a mixture of tritiated compounds formed, 2a-2c; the latter two containing small amounts of protium substitution. Tritium NMR also indi