2,3-Dihydro-1H-naphtho[1,8- de ][1,3]diphosphinines
✍ Scribed by Tarasevych, Arkadii; Rozhenko, Alexander; Röschenthaler, Gerd-Volker; Shevchenko, Igor
- Book ID
- 118021653
- Publisher
- Taylor and Francis Group
- Year
- 2011
- Tongue
- English
- Weight
- 481 KB
- Volume
- 186
- Category
- Article
- ISSN
- 1042-6507
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📜 SIMILAR VOLUMES
In the title molecule, C 19 H 17 NO, the dihedral angle between the naphthyl fused-ring system and the phenyl ring is 17.4 (1) . In the absence of hydrogen-bonding interactions andstacking interactions, the crystal structure is stabilized by van der Waals interactions.
In the title compound, C~21~H~21~NOS, the oxazine ring is not planar and displays a half-chair conformation. The phenyl and naphthalene ring systems make a dihedral angle of 78.65 (7)°.
In the title compound, C 24 H 17 Cl 2 NO, the oxazine ring is distorted and adopts an envelope conformation. The dihedral angle between the dichlorophenyl ring and the naphthyl system is 85.30 ( 13) . An intramolecular N-HÁ Á ÁCl hydrogen bond is observed.
## Abstract magnified image Naphtho[2,1‐__b__]pyran nuclei are prevalent in natural products with significant biological and medicinal properties. 3,3‐Disubstituted 3__H__‐naphtho[2,1__‐b__]pyrans are photochromic and find use in electronic display systems, ophthalmic lenses, optical switches, and