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2,3-Dichloro-5,6-dicyano-1,4-benzoquinone, a mild catalyst for the formation of carbon-nitrogen bonds

✍ Scribed by Jean Jacques Vanden Eynde; Florence Delfosse; Pascal Lor; Yves Van Haverbeke


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
283 KB
Volume
51
Category
Article
ISSN
0040-4020

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Several methods are available for the synthesis of coumarin ring systeml. We nQy report a new method for the synthesis of coumarins by oxidative cyclisation of some substituted 2allylphenols by 2,3=dichloro-5,6-dicyano-1,4-bensoguinone 0). 7-Allyloxy-3-methylflavone2 on Claisen rearrangement b vacu