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ChemInform Abstract: The [2 + 2] Cycloaddition Reaction of Ethynylated 2H-Cyclohepta[b]furan-2-ones with 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone.

✍ Scribed by Taku Shoji; Junya Higashi; Shunji Ito; Masafumi Yasunami; Noboru Morita

Publisher: John Wiley and Sons
Year: 2012
Weight: 27 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201207079

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Charge-transfer interactions of octaethylporphycenatozinc(II), ( OEPc ) Zn with 2,6-dichloro-3,5-dicyano-1,4-benzoquinone, DDQ, in non-aqueous solvents are reported. Both optical absorption and cyclic voltammetry studies reveal the formation of stable charge-transfer complexes between ( OEPc ) Zn an