The title compound, C 20 H 13 Br 3 Cl 2 O 2 , arose unexpectedly as the product of a bromination reaction. The bromo substituents at the central C-C single bond are trans to each other ] and the dihedral angle between the mean planes of the aromatic ring systems is 38.28 (10) .
2,3-Dibromo-3-(5-bromo-2-methoxyphenyl)-1-(2,4-dichlorophenyl)propan-1-one
β Scribed by Narayana, B. ;Mayekar, Anil N. ;Yathirajan, H. S. ;Sarojini, B. K. ;Kubicki, Maciej
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 837 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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β¦ Synopsis
In the title molecule, C~16~H~11~Br~3~Cl~2~O~2~, the chain Br atoms are in trans positions [BrβCβCβBr torsion angle is 179.0β (2)Β°]. The two benzene rings make a dihedral angle of 39.54β (15)Β°. The crystal packing is determined by van der Waals forces; some weak ΟβΟ interactions between the benzene rings of neighbouring molecules are also possible [the distance between their centroids is 3.753β (5)β Γ ]. Intermolecular CβH...Br interactions are also present.
π SIMILAR VOLUMES
In the title compound, C 21 H 17 Br 3 O 3 , the two aromatic residues are almost coplanar with one another [dihedral angle = 9.92 (6) ]. The two Br atoms at the Csp 3 atoms are in a trans conformation. Related literature For background, see: Yathirajan et al. (2007).
Br 3 FOS, a chalcone derivative, are in the normal ranges. The bromo substituents at the central C-C single bond are trans to each other.
In the title compound, C~17~H~12~Br~3~Cl~2~NO, the mean planes of the 3,5-dibromo-4-phenyl and 2,4-dichlorophenyl groups make a dihedral angle of 72.4β (2)Β°. The dihedral angles between the 2-bromoprop-2-en-1-one group and the two phenyl ring groups (3,5-dibromo-4-phenyl and 2,4-dichlorophenyl) are 7