The title compound, C~21~H~14~Cl~2~O, was prepared from biphenyl-4-carbaldehyde and 2,4-dichloroacetophenone. Single crystals were obtained from acetone. The compound crystallizes with four molecules in the asymmetric unit, all of which deviate significantly from planarity.
3-(Biphenyl-4-yl)-2,3-dibromo-1-(2,4-dichlorophenyl)propan-1-one
✍ Scribed by Yathirajan, H. S. ;Mayekar, A. N. ;Narayana, B. ;Sarojini, B. K. ;Bolte, Michael
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 121 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the molecule of the title compound, C 21 H 17 N 3 O, the nearly planar benzotriazole ring system is oriented with respect to the planar rings C (benzoyl) and D (terminal phenyl) at dihedral angles of 58.52 (1) and 77.16 (1) , respectively. In the crystal structure, intermolecular C-HÁ Á ÁN hydrog
The two benzene rings of the title compound, C 18 H 20 O 5 , are almost parallel, with a dihedral angle of 1.3 (2) . The hydroxy group forms intermolecular O-HÁ Á ÁO hydrogen bonds which link the molecules into infinite chains along the c axis.
In the title molecule, C 17 H 14 Cl 2 O 3 , the methoxy groups are almost coplanar with the attached benzene ring. The molecules are linked via intermolecular C-HÁ Á ÁO interactions into wave-like chains along the b axis.
The title compound, C~16~H~12~Cl~2~O, exhibits second-order nonlinear optical properties as it crystallizes in a non-centrosymmetric space group. The dihedral angle between the benzene rings is 34.02 (6)°. Intermolecular C—H...O interactions link the molecules to form chains along the __c__ axis.