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[2+2] thermal cyclodimerization of cis, trans-1,3-cyclooctadiene

✍ Scribed by Padwa, Albert; Koehn, William; Masaracchia, Joseph; Osborn, C. L.; Trecker, D. J.

Book ID
120161478
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
763 KB
Volume
93
Category
Article
ISSN
0002-7863

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1 1,3-cis, trans-Cyclooetadiene ( 2) is an intriguing diene when considered in terms of the Diels-Alder reaction. A concerted 1,4-cycloaddition of an appropriate dienophile would give the unknown bicyclic system 2. This is to be contrasted with the possible 2 + 2 addition of the dienophile to ~ whi