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The thermal dimerization of cis,trans-1,3-cyclooctadiene

✍ Scribed by C.L. Osborn; D.J. Trecker; Albert Padwa; William Koehn; Joseph Masaracchia

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
180 KB
Volume
11
Category
Article
ISSN
0040-4039

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## Abstract The thermal reaction of 1,3‐butadiene (BD) has been studied between 464 and 557Β°K at pressures between 49 and 450 torr. The products are 4‐vinylcyclohexene (VCH) and __cis__, __cis__‐cycloocta‐1,5‐diene (COD), and their formations are second order. The rate constant (in 1/mol Β· sec) for