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22. Stereospecific synthesis of the 24-epimeric 5α-stigmast-22-en-3β-ols and 5α-stigmastan-3β-ols

✍ Scribed by W. Sucrow; M. Slopianka; P. Polyzou-Caldeira


Book ID
118924660
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
151 KB
Volume
5
Category
Article
ISSN
0022-4731

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Stereospecific total synthesis of rac. 5
✍ W. Nagata; T. Terasawa; T. Aoki 📂 Article 📅 1963 🏛 Elsevier Science 🌐 French ⚖ 178 KB

THE total synthesis of several steroids (1.2) has previously been reported from this laboratory. In this communication a straightforward total synthesis of rec. 5a-preQnan-3~-ol-20-one (XIIIa) is reported. '3 All melting points were measured on Kofler block and corrected. '