2,2-Divinyladamantane: a new substrate for the modification of silicon surfaces

✍ Scribed by Luc Giraud; Vroni Huber; Titus Jenny

• Publisher: Elsevier Science
• Year: 1998
• Tongue: French
• Weight: 538 KB
• Volume: 54
• Category: Article
• ISSN: 0040-4020
• DOI: 10.1016/s0040-4020(98)83047-0

✦ Synopsis

2,2-Divinyladamantane has been readily obtained in six steps from 2-adamantanone. The key steps were a Wittig-Homer-Emmons reaction, an ortho ester Claisen rearrangement using the microwave heating technique and a selenoxide elimination.