Bis[bis(1,10-phenanthroline)chlorocopper(II)] benzene-1,2,4,5-tetracarboxylate(2±) dihydrate
(2,2′-Dicarboxy-4,4′-carbonyldibenzoato)bis(1,10-phenanthroline)copper(II) dihydrate
✍ Scribed by Hao, Lu-Jiang ;Yu, Tong-Li
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 863 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Cu(C 17 H 8 O 9 )(C 12 H 8 N 2 ) 2 ]Á2H 2 O, the Cu II cation is hexacoordinated by two carboxylate O atoms from one of the two deprotonated carboxyl groups in the 3,3,4,4-benzophenone tetracarboxylate, and four N atoms from two 1,10-phenanthrolines, showing a slightly distorted octahedral geometry. A network of hydrogen bonds links the units into a three-dimensional structure.
📜 SIMILAR VOLUMES
In the title compound, 2C~2~H~8~N^+^·C~10~H~4~O~8~ ^2−^·2C~12~H~8~N~2~, dimethylammonium cations, 2,5-dicarboxybenzene-1,4-dicarboxylate anions and 1,10-phenanthroline molecules are linked by N—H...N and N—H...O hydrogen bonds into a network structure. The 2,5-dicarboxybenzene-1,4-dicarboxylate anio
l-Terephthalato-bis[aquachloro(1,10-phenanthroline)copper(II)] l-terephthalato-bis-[diaqua(1,10-phenanthroline)cuprate(II)] dichloride dihydrate