2,2′-Bi-1,3-diselenole
✍ Scribed by Hansen, Karsten ;Thorup, Niels ;Johannsen, Ib ;Bechgaard, Klaus
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 254 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title structure (commonly known as 2,2 0 ,5,5 0 -tetraselenafulvalene or tetraselenafulvalene), C 6 H 4 Se 4 , contains two independent molecules, one of which is planar and centrosymmetric. The other molecule has a pronounced boat conformation and no imposed crystallographic symmetry. Corresponding bond lengths in the two molecules are similar. A few short intermolecular SeÁ Á ÁSe contacts are present.
📜 SIMILAR VOLUMES
## Abstract The reaction of 2,5‐dimethyl‐3,4‐diselenocyanato‐1__H__‐pyrrole by NaBH~4~ or NaOCH~3~ led to tetraselenide **7** in quantitative yield. Treatment of protected tetraselenide **8** with LiAlH~4~ afforded the aluminum complex intermediate that was converted into pyrrole‐annelated 1,3‐dise