𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2,2′-[1,1′-(Ethylenedioxydinitrilo)diethylidyne]diphenol

✍ Scribed by Wang, Li ;He, Xueni ;Sun, Yinxia ;Xu, Li

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
278 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 18 H 20 N 2 O 4 , has been characterized structurally by 1 H NMR and X-ray crystallography. The molecule is centrosymmetric. The two benzene rings are parallel to each other with a perpendicular interplanar spacing of ca 1.4 A ˚. Intramolecular O-HÁ Á ÁN hydrogen bonds are formed between the oxime and hydroxy groups.

📜 SIMILAR VOLUMES

4,4′-Dimethyl-2,2′-[1,1′-(ethane-1,2-diy
4,4′-Dimethyl-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenol
✍ Chakkaravarthi, G. ;Anthonysamy, A. ;Balasubramanian, S. ;Manivannan, V. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 537 KB

The title compound, C~20~H~24~N~2~O~2~, is a Schiff base compound derived from the condensation of 2-hydroxy-5-methylacetophenone and 1,2-diaminoethane in ethanol. The molecule has crystallographic twofold rotation symmetry. The molecular structure is stabilized by weak intramolecular O—H...N intera

2,2′-[1,1′-(Propane-1,3-di­yl)bis­(nitri
2,2′-[1,1′-(Propane-1,3-di­yl)bis­(nitrilo­ethyl­idyne)]diphenol
✍ Selvakumar, J. ;Varghese, Babu ;Raghunathan, V. S. ;Nagaraja, K. S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 232 KB

The structure of the title compound, C 19 H 22 N 2 O 2 , shows two intramolecular O-HÁ Á ÁN hydrogen-bonding interactions. The packing is stabilized through van der Waals contacts and two C-HÁ Á Á interactions.

(E,E)-4,4′-Dimethyl-2,2′-(1,1′-dibenzyla
(E,E)-4,4′-Dimethyl-2,2′-(1,1′-dibenzylazino)diphenol
✍ Chang, Jian-Guo ;Li, Ji-Kun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 730 KB

The title molecule, C 30 H 28 N 2 O 2 , (I), resides on a crystallographic inversion centre located at the midpoint of the N-N bond. It contains an intramolecular O-HÁ Á ÁN interaction [OÁ Á ÁN = 2.572 (2) A ˚] and a weak C-HÁ Á ÁN contact [CÁ Á ÁN = 2.752 (2) A ˚]. There are no intermolecular inter

(E,E)-4,4′,6,6′-Tetrachloro-2,2′-(1,1′-a
(E,E)-4,4′,6,6′-Tetrachloro-2,2′-(1,1′-azinodiethylene)diphenol
✍ Chang, Jian-Guo ;Liu, Xiao-Hong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 952 KB

The title compound, C 18 H 16 Cl 4 N 2 O 2 , was synthesized by the reaction of 1-(3,5-dichloro-2-hydroxyphenyl)propan-1-one with hydrazine hydrate. The molecule has a centre of symmetry at the mid-point of the N-N bond. The crystal structure is stabilized by intramolecular O-HÁ Á ÁN and intermolecu