2,10,11-Trioxatricyclo[4,4,4,01,6]tetradecane: a stable orthoester
β Scribed by Banyard, S. H. ;Dunitz, J. D.
- Book ID
- 117859970
- Publisher
- International Union of Crystallography
- Year
- 1976
- Weight
- 312 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0567-7408
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π SIMILAR VOLUMES
In the title compound, C 18 H 24 O 2 , one of the cyclohexane rings adopts a chair conformation and the other adopts a boat conformation. Molecules are linked by intermolecular O-HΓ Γ ΓO hydrogen bonds, forming ribbons along the b axis.
1998 structure structure (organic substances) K 9000 46 -031 9-Methyl-8,11,12-trioxatricyclo [7.2.1.O 2,7 ]dodeca-2,4,6-trien-10-one. -The structure of the title compound (I), unexpected reaction product of salicylaldehyde and pyruvic acid, is elucidated by X-ray diffraction analysis. -(EILERS, F.;
In a previous study we found that when ll,ll-dichloro-1,6-methano[lOlannulene (1) was treated with methyllithium in the presence of 1,3-diphenylisobenzofuran (DPIBF), only one carbenoid derived product was obtained. 2 The structure of this