In the paper, we compare the results of our ab initio calculations for the ro-vibrational branching ratios resultmg from a (3 + 1) REMPI of H, via the B 'X: state with the experimental data of Pratt, Poliakoff. Dehmer and Dehmer. These results indicate that non-Franck-Condon effects are less importa
(2+1) REMPI of NO via the D 2Σ+ state: rotational branching ratios
✍ Scribed by H. Rudolph; S.N. Dixit; V. McKoy; Winifred M. Huo
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 222 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0009-2614
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It is shown that there are some advantages to determining ground state population distributions of H2 by 1 + 1 REMPI using the C 'II, (u' ~0) state as the intermediate state. The state distribution can be deduced more directly from the ion signal, in addition, a much improved sensitivity of < I .7x
## Recent experiments by Bergeman and tire led to a dipole moment of l&l = 1 .lO k 0.03 D for the v = 3 vibrational level of the A\* C' stzte of NO, whereas conflgxation interaction (CI) stud& by Green led to p = 0.39 D (N+O-), a serious discrepancy. We report herein ab initjo generalized valence