In the paper, we compare the results of our ab initio calculations for the ro-vibrational branching ratios resultmg from a (3 + 1) REMPI of H, via the B 'X: state with the experimental data of Pratt, Poliakoff. Dehmer and Dehmer. These results indicate that non-Franck-Condon effects are less importa
State-selective detection of H2 BY 1+1 REMPI via the C 1Πu (ν′=0, J′) states
✍ Scribed by A.H. Kung; T. Trickl; N.A. Gershenfeld; Y.T. Lee
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 352 KB
- Volume
- 144
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
It is shown that there are some advantages to determining ground state population distributions of H2 by 1 + 1 REMPI using the C 'II, (u' ~0) state as the intermediate state. The state distribution can be deduced more directly from the ion signal, in addition, a much improved sensitivity of < I .7x lo5 molecules/cm3 per quantum state is achieved.
📜 SIMILAR VOLUMES
The Born-Oppenheimer energies have been computed for the C al-Iu state of H 2 by the variational method in the interval 0.8 ~< R ~< 12 a o and the electronic transition moments for the Werner band determined. The energies are by a few hundredths of a wavenumber lower than ever reported and the compu