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2-Trifluoroacetyl aminoindoles as useful intermediates for the preparation of 2-acylamino indoles

โœ Scribed by John E. Mangette; Xuemei Chen; Ravi Krishnamoorthy; A. Samuel Vellekoop; Adam J. Csakai; Fatoumata Camara; William D. Paquette; Hong-Jun Wang; Hidenori Takahashi; Roman Fleck; Gregory P. Roth

Book ID
104098840
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
414 KB
Volume
52
Category
Article
ISSN
0040-4039

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โœ Patrick D Bailey; Sean P Hollinshead ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 228 KB

~ A simple three step route to 3-(indol-2-yl)--propenoate derivatives of tryptamine has been developed, involving the base-induced ring-opening of protected tetrahydro-8-carbolines that result from a modified Pictet-Spengler reaction. Several recent syntheses of indole alkaloids have utilised Z-prop