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2-Tolylpyrrolines and the Rearrangement and Hydrolysis of Aryl Cyclopropyl Ketimines

โœ Scribed by Cloke, John B.; Baer, Louis H.; Robbins, James M.; Smith, Gustavus E.

Book ID
127360060
Publisher
American Chemical Society
Year
1945
Tongue
English
Weight
488 KB
Volume
67
Category
Article
ISSN
0002-7863

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Stereospecific 1,2-rearrangement of cycl
Stereospecific 1,2-rearrangement of cyclopropyl group. Synthesis of chiral ฮฑ-cyclopropyl ketones and ฮฑ-cyclopropyl aldols
โœ Masato Shimazaki; Hisaaki Hara; Keisuke Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 294 KB

Stereospecific 1,2-rearrangement of cyclopropyl group is described as an efficient route to stereo-defined a-cyclopropyl ketones and cr-cyclopropyl aldols. Acceleration of the reaction by the introduction of trimethylsilyl (TMS) group to the a-position of cyclopropyl group is also noted. ## Cyclop