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2-Thiazolines in organic synthesis. Formation of .beta.-hydroxy aldehydes with protected hydroxy groups. Synthesis of homoallylic alcohols

✍ Scribed by Meyers, A. I.; Durandetta, James L.; Munavu, Raphael


Book ID
115453349
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
732 KB
Volume
40
Category
Article
ISSN
0022-3263

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The 1-~(2-chloro-4-methyl)phenyl]-4-methoxypiperidin-4-yl [Ctmp, as in (14a)] has an acid lability similar to that of the 4-methoxytetrahydropyran-4-yl (Mthp) protect= group under mild hydrolytic conditions [pH 2-31; however, under the relatively more drastic conditions required for the complete rem