2-tert-Butyl-4-(phenylsulfonyl)-1,2,3,4-tetrahydropyrrolo[3,4-b]indole
β Scribed by Kishbaugh, Tara L. S. ;Gribble, Gordon W. ;Jasinski, Jerry P.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 840 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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π SIMILAR VOLUMES
The indole and pyrrolidine ring systems of the title compound, C 23 H 20 N 2 O 2 S, are essentially coplanar. The angle between the planes of the phenylsulfonyl group and the indole ring system is 77.0 (1) . The benzyl ring and the pyrroloindole plane are nearly perpendicular, with an angle between
The indole and pyrrolidine ring systems of the title compound, C 24 H 22 N 2 O 3 S, are essentially coplanar. The angle between the planes of the phenylsulfonyl group and the indole ring system is 89.1 (2) , which is characteristic of 1-(phenylsulfonyl)indoles. The benzyl ring is nearly perpendicula
The N-phenylsulfonyl derivative (2) of the previously unknown fused heterocycle 4Hfuro[3,4-blindole is synthesized from indole-3-carboxaldehyde (2) in 28% yield and undergoes a Diels-Alder reaction with benzyne to give 5H-benzo[b]carbazole (11) in -33% yield after deoxygenation and deprotection.
## Abstract For the first time, tetracyclic compounds, namely, furo[2β²,3β²:3,4]cyclohepta[1,2βb]indoles were synthesized by recyclization of __ortho__βsubstituted aryldifurylmethanes containing __tert__βbutyl groups at C5 positions of the furan rings. It was shown that [2β(benzoylamino)phenyl]bis(5β