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2-(4-Methoxybenzyl)-4-(phenylsulfonyl)-1,2,3,4-tetrahydropyrrolo[3,4-b]indole

โœ Scribed by Kishbaugh, Tara L. S. ;Gribble, Gordon W. ;Jasinski, Jerry P.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
735 KB
Volume
63
Category
Article
ISSN
1600-5368

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โœฆ Synopsis


The indole and pyrrolidine ring systems of the title compound, C 24 H 22 N 2 O 3 S, are essentially coplanar. The angle between the planes of the phenylsulfonyl group and the indole ring system is 89.1 (2) , which is characteristic of 1-(phenylsulfonyl)indoles. The benzyl ring is nearly perpendicular to the pyrroloindole unit, with an angle between the planes of 82.2 (2) .


๐Ÿ“œ SIMILAR VOLUMES


2-Benzyl-4-(phenylsulfonyl)-1,2,3,4-tetr
โœ Kishbaugh, Tara L. S. ;Gribble, Gordon W. ;Jasinski, Jerry P. ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 798 KB

The indole and pyrrolidine ring systems of the title compound, C 23 H 20 N 2 O 2 S, are essentially coplanar. The angle between the planes of the phenylsulfonyl group and the indole ring system is 77.0 (1) . The benzyl ring and the pyrroloindole plane are nearly perpendicular, with an angle between

4-(phenylsulfonyl)-4H-furo[3,4-b]indole
โœ Mark G. Saulnier; Gordon W. Gribble ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 237 KB

The N-phenylsulfonyl derivative (2) of the previously unknown fused heterocycle 4Hfuro[3,4-blindole is synthesized from indole-3-carboxaldehyde (2) in 28% yield and undergoes a Diels-Alder reaction with benzyne to give 5H-benzo[b]carbazole (11) in -33% yield after deoxygenation and deprotection.

3-(4-Chlorophenyl)-6-(4-methoxybenzyl)-1
โœ Xu, Feng ;Hu, Wei-Xiao ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 444 KB

The title compound, C 16 H 13 ClN 4 O, crystallizes with two unique molecules in the asymmetric unit; these differ in the orientation of the methoxy group. In both molecules, the chlorophenyl ring is almost coplanar with the central tetrazine ring, but the methoxyphenyl ring is twisted. The crystal