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2-Pyrones. XIII. 1 The Chemistry of Coumalic Acid and its Derivatives

โœ Scribed by Wiley, Richard H.; Knabeschuh, Louis H.


Book ID
120068087
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
401 KB
Volume
77
Category
Article
ISSN
0002-7863

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The preparation of NaS02CF3, KS02CF3 and AgS02CF3 from HS02CF3 and the corresponding carbonates is described. CF3S(0)N[Si(CH3)3]2 or CF3S(0)NHSi(CH3)3 react with SOC12 to form CF3S(0)N=S=0. A compound with two sulfur atoms in oxidation state +4. The reaction products of CF3S(0)NC0 with CHSOH, CHICOO