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2-Pyridylmetallocenes: part 2 [1]. Cyclomercuration of 2-pyridyl-cyrhetrene. Molecular structures of 2-pyridyl-cyrhetrene and 1-chloromercurio-2-(2-pyridyl)-cyrhetrene

✍ Scribed by Karlheinz Sünkel; Stefan Weigand


Book ID
116573065
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
660 KB
Volume
21
Category
Article
ISSN
1387-7003

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1-(2-Pyridyl)­pyrrolidine-2-thione
✍ Datt, Michael S. ;Koning, Charles B. de ;Fernandes, Manuel A. ;Michael, Joseph P 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 232 KB

The title compound, C 9 H 10 N 2 S, was prepared by thionation of 1-(2-pyridyl)pyrrolidin-2-one with phosphorus pentasul®de. In the crystalline state, the plane of the pyrrolidine-2-thione ring is twisted by about 21 relative to the pyridine ring. In the crystal structure, molecules are associated b