2-Norbornyl anion. Selectivity in exo-endo proton capture
β Scribed by Stille, J. K.; Feld, W. A.; Freeburger, M. E.
- Book ID
- 127132010
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 606 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The effect of substituents at C4, 5, 6 and 7 on solvolysis rates and products of 2-exo-and 2-endo-norbornyl tosylates confirms that differential carbon participation is responsible for varying exo/endo rate and product ratios.
## Abstract The solvolysis rates and products of the 6β__exo__βsubstituted 2β__exo__β **1a**β**1u**, and 2β__endo__βnorbornyl __p__βtoluenesulfonates **2a**β**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants Ο of