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(2-Nitro ethyl)phenyl and cyanophenyl glycosides from the fruits of Diploclisia glaucescens

โœ Scribed by Jayasinghe, U. L. B.; Hara, N.; Fujimoto, Y.


Book ID
126664982
Publisher
Taylor and Francis Group
Year
2007
Tongue
English
Weight
138 KB
Volume
21
Category
Article
ISSN
1478-6419

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โœ Biao Yu; Zunyi Yang ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 126 KB

1,2-Migration and concurrent glycosidation of ethyl(phenyl) 2,3-orthoester-1-thio-ฮฑ-L-rhamnopyranosides under the action of TMSOTf readily afforded the corresponding 2-S-ethyl(phenyl)-2-deoxy-ฮฒ-glycosides, ready precursors to 2-deoxy-ฮฒ-glycosides.