2-Methyl-3,3,10-triphenyl-3,4-dihydronaphth[2,1-c]azepine-1,5-dione
✍ Scribed by Zhao, Bao-Guo ;Usman, Anwar ;Razak, Ibrahim Abdul ;Fun, Hoong-Kun ;Chantrapromma, Suchada ;Xu, Jian-Hua
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 484 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 33 H 25 NO 2 , the azepine ring adopts a half-chair conformation. The molecules are packed into a three-dimensional network by three intermolecular CÐHÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.042 wR factor = 0.120 Data-to-parameter ratio = 15.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.003 A R factor = 0.044 wR factor = 0.115 Data-to-parameter ratio = 14.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 19 H 14 F 3 N 3 O 3 S, is built up from pyrazolinone, thiophene, phenyl rings and tri¯uoropropanedicarbonyl moieties. Examination of the ÐC N and ÐC O bond lengths reveals that there is no electron delocalization over the molecule.