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2-Hydroxycyclohexaneacetic Acid Lactones as Intermediates in the Synthesis of Hydrogenated Phenanthrenes

✍ Scribed by Fry, Edward M.


Book ID
126223251
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
700 KB
Volume
17
Category
Article
ISSN
0022-3263

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A simple and safe route to the D-xylone-l,4-1actone derivative 3, a key intermediate for the synthesis of the spiroketal fragment in calyculin A (1) has been explored without the use of hazardous diazomethane on a large scale.