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2-[Hydro­xy(2-pyridyl)­methyl]-2-cyclopenten-1-one: the Baylis–Hillman adduct of 2-pyridine­carbox­aldehyde and 2-cyclo­penten-1-one

✍ Scribed by Huo, Fangjun ;Yin, Caixia ;Guo, Wei ;Xia, Chizhong


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
379 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


A view of the molecular structure of (I) with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitrary radii.


📜 SIMILAR VOLUMES


The Baylis–Hillman adduct of 4-nitro­ben
✍ Huo, Fangjun ;Yin, Caixia ;Guo, Wei ;Xia, Chizhong ;Yang, Pin 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 151 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.056 wR factor = 0.146 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Synthesis of enantiomerically pure 4-ace
✍ Masayuki Sato; Taiko Hirokawa; Hanae Hattori; Akemi Toyota; Chikara Kaneko 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 414 KB

Addition of molecular fluorine to cis-2-cyclopentene-1 ,Cdiol gave the c&anti adduct stereoselectively. This meso diol was dissymmetrized by means of acetylation under lipase catalysis to afford the monoacetate with a high enatiomeric purity. Oxidation of the monoacetate followed by elimination of h