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2-Furyloxirane: 1. Anionic and coordination homo- and copolymerization

✍ Scribed by Hilmi Amri; Mohamed Naceur Belgacem; Alessandro Gandini

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
528 KB
Volume
37
Category
Article
ISSN
0032-3861

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✦ Synopsis

2-Furyloxirane (FO) was polymerized by various anionic and coordination initiators both in bulk and solution. The corresponding polyethers had relatively low DPns (up to about 100) and possessed relatively irregular structures arising from propagation reactions involving both Ca and C/3 oxirane ring opening, except when aluminium isopropoxide was used as catalyst. The glass transition temperature (Tg) of these polymers was always lower than room temperature and approached 15Β°C for the highest molecular weight. Propylene oxide did not copolymerize with FO, whereas butylene oxide gave copolymers, but the reactivity of FO remained much higher and the products were therefore rich in this comonomer unit.

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