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Anionic homo- and block copolymerization of vinylferrocene

✍ Scribed by Oskar Nuyken; Volker Burkhardt; Christian Hübsch

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
427 KB
Volume
198
Category
Article
ISSN
1022-1352

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✦ Synopsis

Vinylferrocene was polymerized by means of anionic initiators such as n-BuLi, s-BuLi and distyryl disodium in tetrahydrofuran as solvent. In all cases the polymerization shows the characteristics of a living polymerization. Depending on the sequence of the monomer addition, either block copolymers of the ABA or the AB type were synthesized.

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