In the title compound, C 19 H 17 BrO 6 , the biphenyl twist angle is 43.6 (1) . All three ester groups are planar and make dihedral angles of 61.0 (1), 70.6 (1) and 14.1 (1) with the attached benzene ring.
2-Ethyl 3,4-dimethyl 4′-methylbiphenyl-2,3,4-tricarboxylate
✍ Scribed by Bhaskaran, Sundari ;Velmurugan, D. ;Ravikumar, K. ;Mohana Krishnan, A. K. ;Prakash, C.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 250 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, C 20 H 20 O 6 , the biphenyl twist angle is 48.2 (1) . All three ester groups are planar and they make dihedral angles of 63.6 (1), 56.8 (1) and 41.6 (1) with the attached benzene ring. C-HÁ Á ÁO interactions contribute to both molecular and crystal stability.
📜 SIMILAR VOLUMES
The title compound, C 16 H 17 NO 5 , crystallizes with two molecules in the asymmetric unit. The dihedral angles between the furan and benzene rings are 26.38 (13) and 28.52 (14) . The molecules are linked by N-HÁ Á ÁO hydrogen bonds, leading to dimers.
Single-crystal X-ray study T = 292 K Mean '(C±C) = 0.002 A Ê R factor = 0.030 wR factor = 0.095 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~18~H~19~NO~5~, synthesized __via__ a thiazole carbene-mediated multicomponent reaction, has a crystal structure stabilized by π–π stacking interactions involving the phenyl and furan rings.