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2-Deoxy sugars Part XIII. 1,3-dideoxy-d-erythro-hexulose

✍ Scribed by Barbara F. West; K.Venkatramana Bhat; W.Werner Zorbach


Book ID
108308095
Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
695 KB
Volume
8
Category
Article
ISSN
0008-6215

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Investigations towards the synthesis of
✍ Thomas MΓΌller; Richard R Schmidt πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 252 KB

The synthesis of the target molecule 1 is based on thexyldimethylsilyl 4-O-acetyl-2,3,6-trideoxy-3-Cmethylene-~-D-erythro-hexopyranoside (7) which is readily obtained via two different mutes from tri-O-acetyl-Dglacal (2). Replacement of the anomeric silyl group by the diethylphosphite group, then pe