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2′-Deoxy-2′-alkoxylaminouridines: Novel 2′-substituted uridines prepared by intramolecular nucleophilic ring opening of 2,2′-O-anhydrouridines

✍ Scribed by David P. Sebesta; Sarah S. O'Rourke; Rogelio L. Martinez; Wolfgang A. Pieken; Danny P.C. McGee


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
953 KB
Volume
52
Category
Article
ISSN
0040-4020

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Intramolecular ring opening of a 2,3-epo
✍ Jun'ichi Uenishi; Mitsuhiro Motoyama; Yoshitaka Nishiyama; Yuichi Hirota; Yuki K 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 866 KB

Stereospecific ring openings of optically active 2,3epoxy alcohols were performed by the reaction of 1, 3,5, and 7 with curbon disulfide and sodium hydride to give the five-membered xanthates 2, 4, 6, and 8. Both enantiomers of 2-mercapto-l,3-diol triacetates, 11 and 14, were derived from 4 and 6, r