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2-cyanopenta-(2E,4)-dienoic acid and its amide

✍ Scribed by I. R. Gol'ding; P. V. Petrovskii; Yu. G. Gololobov

Publisher: Springer
Year: 1998
Tongue: English
Weight: 155 KB
Volume: 47
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf02498967

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Di-n-butyl telluride, 2-bromoacetylisobutylamide (or 2-bromoacetylpiperidide) react directly with saturated or +unsaturated aldehydes at room temperature in the presence of potassium carbonate(s) to afford (2E)-, or (2E, 4E)-unsaturated carboxylic acid amides, respectively, in excellent yields with