2-Cyano-1,3-dicarbonyl compounds with antiallergic activity
โ Scribed by Buckle, Derek R.; Cantello, Barrie C. C.; Smith, Harry; Spicer, Barbara A.
- Book ID
- 123613053
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 626 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0022-2623
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๐ SIMILAR VOLUMES
Depending on conditions, the condensation of 2-amino-3-cyano-4,5,6,7-tetrahydroindole with 8-dicarbonyl compounds leads to 2-methyl-4-oxo-or 4-methyl-2-oxo-10-cyano-6,7,8,9tetrahydropyrimido[l,2-a]indoles via the intermediate compounds: 2-(3-ethoxy-carbonylprop-2-en-2-yl amino) and 2- (l,3-dioxobuty
A very efficient photo-sensitized oxidation of 2-(2-furyl)-1,3-dicarbonyl compounds 1 afford directly hydroperoxides 2 in stereoselective way. Compounds 2, easily isolated, can be conveniently employed in a selective epoxidation of trisubstituted allylic alcohols by a Sharpless-type procedure.