The title compound, C 16 H 14 Cl 2 N 2 , was prepared by the reaction of hydrazine with 2-chloroacetophenone at room temperature. The molecule has C 2 symmetry with the midpoint of the N-N bond lying on the twofold axis.
(2-Chloroanilino)acetophenone
✍ Scribed by Anilkumar, Haleyur G. ;Yathirajan, Hemmige S. ;Nagaraja, Padmarajaiah ;Bolte, Michael
- Book ID
- 104484718
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 211 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title complex, C 14 H 13 BrClNO, adopts a helical motif built up from intermolecular O-HÁ Á ÁO interactions with a repeat distance of 8.4 A ˚. Further assembly of the helices forms a parallel square grid array reminiscent of apolar peptide extended packing motifs.
The crystal structure of the title compound, C 14 H 17 ClN 2 OS 2 , is stabilized by intermolecular N-HÁ Á ÁS hydrogen bonds and stacking interactions.
The crystal structure of the title compound, C 10 H 6 Cl 3 NO 3 , establishes that condensation of 2,4,6-trichloroaniline with maleic anhydride gives the title compound at room temperature. There are strong intermolecular NÐHÁ Á ÁO hydrogen bonds [NÁ Á ÁO = 2.832 (2) and 2.867 (2) A Ê ], resulting i