## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
2-Benzylsulfanyl-1H-benzimidazole
✍ Scribed by Yavo, Edi Aimé ;Kakou-Yao, R. ;Coulibaly, Siomenan ;Abou, Akoun ;Tenon, A. Jules
- Book ID
- 104492368
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 472 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the molecule of the title compound, C 14 H 12 N 2 S, the benzimidazole ring system and the phenyl ring form a dihedral angle of 81.36 (7) . The crystal structure exhibits intermolecular C-HÁ Á ÁN and N-HÁ Á ÁN hydrogen bonds.
📜 SIMILAR VOLUMES
A simple and convenient procedure for the preparation of 2-benzylthiobenzimidazoles by the reaction of 2-mercaptobenzimidazole and benzyl bromides in acetone/potassium carbonate condition has been reported and the compounds were screened for their potential antimicrobial activities.
The benzimidazole ring system in the title molecule, C 8 H 8 N 2 S, is planar The imidazole ring does not exhibit a delocalized aromatic bond system. Molecules are linked by N-HÁ Á ÁN hydrogen bonds along the c axis. The crystal structure is further stabilized by C-HÁ Á Á interactions.
Single-crystal X-ray study T = 100 K Mean (C-C) = 0.003 A R factor = 0.052 wR factor = 0.139 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The molecule of the title compound, C 15 H 13 O 2 N 3 , deviates slightly from planarity. There is a strong intramolecular NÁ Á ÁO hydrogen bond of 2.5831 (19) A Ê . The molecule exists in the phenol±imine form and the dihedral angle between the two aromatic ring systems is 14.61 (5) .