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2-(3-Methoxy­salicylideneamino)-1H-benzimidazole

✍ Scribed by Odabąsogˇlu, Mustafa ;Albayrak, Çigˇdem ;Büyükgüngör, Orhan


Book ID
104483187
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
187 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The molecule of the title compound, C 15 H 13 O 2 N 3 , deviates slightly from planarity. There is a strong intramolecular NÁ Á ÁO hydrogen bond of 2.5831 (19) A Ê . The molecule exists in the phenol±imine form and the dihedral angle between the two aromatic ring systems is 14.61 (5) .


📜 SIMILAR VOLUMES


2-(2-Methoxy­phen­yl)-1H-benzimidazole
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Single-crystal X-ray study T = 100 K Mean (C-C) = 0.003 A R factor = 0.052 wR factor = 0.139 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title molecule, C 21 H 18 N 2 O 2 , all bond lengths and angles are normal. Weak intermolecular N-HÁ Á ÁN hydrogen bonds link the molecules into chains along the c axis. The crystal packing is further stabilized by van der Waals forces.

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