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2-Amino­quinolin-4-yl 2,4,6-triisopropyl­benzene­sulfonate

✍ Scribed by Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Rebelo, Ricardo Andrade ;Foro, Sabine ;Schmidt, Boris


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
261 KB
Volume
62
Category
Article
ISSN
1600-5368

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2-Amino­quinolin-8-yl 2,4,6-triisopropyl
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The nearly planar aminoquinoline fragment and the aromatic ring of the triisopropylbenzenesulfonate group of the title compound, C 24 H 30 N 2 O 3 S, form a dihedral angle of 47.9 (2) . Both H atoms of the amino group are involved in intermolecular hydrogen bonds of types N-HÁ Á ÁO (2.56 A ˚) and N-

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The molecular packing of the title compound, C 15 H 11 N 2 O 3 S, is stabilized by a hydrogen-bonded network. The H atoms of the amino group form intermolecular N-HÁ Á ÁN [2.13 (3) A ˚] and N-HÁ Á ÁO [2.46 (3) A ˚] hydrogen bonds. The sulfonyl O atoms are each also involved in intermolecular C-HÁ Á

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In the title compound, [Zn(C 24 H 29 N 2 O 2 S) 2 ], the Zn atom is four-coordinated by the N atoms of the sulfonamide and quinoline groups. The crystal packing is stabilized by intermolecular C-HÁ Á ÁO hydrogen bonds.

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