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2-Amino-4,6-dimethyl­pyrimidine–4-hydroxy­benzoic acid (1/1)

✍ Scribed by Balasubramani, Kasthuri ;Muthiah, Packianathan Thomas ;Lynch, Daniel E.


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
223 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, C~6~H~9~N~3~·C~7~H~6~O~3~, the 2-amino-4,6-dimethylpyrimidine and 4-hydroxybenzoic acid molecules link together via N—H...O and O—H...N hydrogen bonds to form an eight-membered R
~2~
^2^(8) ring. Further hydrogen bonds and C—H...O interactions result in the formation of a three-dimensional network.


📜 SIMILAR VOLUMES


Hydrogen-bonding patterns in 2-amino-4,6
✍ Thanigaimani, Kaliyaperumal ;Muthiah, Packianathan Thomas ;Lynch, Daniel E. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 257 KB

In the title cocrystal, C~6~H~9~N~3~O~2~·C~7~H~7~NO~2~, the 2-amino-4,6-dimethoxypyrimidine molecule interacts with the carboxyl group of the 4-aminobenzoic acid molecule through N—H...O and O—H...N hydrogen bonds, forming a cyclic hydrogen-bonded motif [__R__ ~2~ ^2^(8)]. This motif further self-or

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✍ Balasubramani, Kasthuri ;Muthiah, Packianathan Thomas ;RajaRam, Ramaswamy Karuna 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 308 KB

In the title compound, C 6 H 9 N 3 Á2C 9 H 8 O 2 , an aminopyrimidine-cinnamic acid 1:2 cocrystal, the 2-amino-4,6dimethylpyrimidine molecule forms two eight-membered hydrogen-bonded rings [R 2

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In the title compound, 2C 7 H 7 NO 2 ÁC 6 H 5 NO 2 , the 4-aminobenzoic acid and the nicotinic acid molecules are approximately planar. The crystal structure is stabilized by an extensive network of N-HÁ Á ÁO, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds.

Syntheses and resolutions of new chiral
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The new chiral backbones (R)-(+)-and S-(-)-2-amino-2%-hydroxy-6,6%-dimethyl-1,1%-biphenyl and (R)-(+)-and (S)-(-)-2-amino-2%-hydroxy-4,4%,6,6%-tetramethyl-1,1%-biphenyl were synthesized from o-methylaniline and 2,4-dimethyl-aniline respectively in seven steps. A new resolution method was developed t

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✍ Li, Na ;Wei, Qing 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 288 KB

In the title polymer, {[Cu(C 8 H 4 O 4 )(C 6 H 9 N 3 )(H 2 O)]ÁC 6 H 9 N 3 } n , the Cu II ion approximates a distorted square-pyramidal geometry defined by an NO 4 donor set. Adjacent Cu II ions are bridged by isophthalate dianions to form a one-dimensional chain. Chains interact throughstacking in

2,6-Bis(4,6-dimethoxy­pyrimidin-2-yl­oxy
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The title compound, C 19 H 18 N 4 O 8 , belonging to the pyrimidinyloxybenzoic acid family, exhibits herbicidal properties. The crystal structure is stabilized by C-HÁ Á ÁO and O-HÁ Á ÁN intermolecular hydrogen bonds.