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2-Amino-4-(4-chloro­phen­yl)-6-morpholinopyridine-3,5-dicarbonitrile

✍ Scribed by Tu, Shu-Jiang ;Li, Tuan-Jie ;Zhu, Song-Lei ;Zou, Xiang ;Wang, Qian

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
328 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 17 H 14 ClN 5 O, was synthesized by the reaction of malononitrile with 4-chlorobenzaldehyde and morpholine in glycol under microwave irradiation. X-ray analysis reveals that the morpholine ring is in a chair conformation. In the crystal structure, intermolecular N-HÁ Á ÁO, C-HÁ Á ÁN and N-HÁ Á ÁN hydrogen bonds form a three-dimensional network.

📜 SIMILAR VOLUMES

trans-4-(4-Chloro­phen­yl)-2-[(2-chloro­
trans-4-(4-Chloro­phen­yl)-2-[(2-chloro­phen­yl)(3-pyridylmethyl­amino)meth­yl]-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide
✍ Sun, Feng-Mei ;Tian, Man-Man ;Luo, Zai-Gang ;Shi, De-Qing 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 318 KB

In the title compound, C 24 H 25 Cl 2 N 2 O 3 P, the P atom adopts a distorted tetrahedral configuration. Weak intermolecular N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds are observed, and C-HÁ Á Á interactions also contribute to the crystal packing.

4-{[3-(2-Chloro­phen­yl)-1,2,4-oxadiazol
4-{[3-(2-Chloro­phen­yl)-1,2,4-oxadiazol-5-yl]meth­yl}-1-[(2,6-dimethyl­phen­yl)amino­carbon­yl­meth­yl]piperazine
✍ Wang, Hai-Bo ;Pu, Yue-Qing ;Chen, Jia-Hui ;Wang, Jin-Tang 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

The title compound, C 23 H 26 ClN 5 O 2 , was synthesized by the reaction of 4- [(2,6-dimethylphenyl)aminocarbonylmethyl]piperazine and 5-chloromethyl-3-(2-chlorophenyl)-1,2,4oxadiazole. In the structure, there are intramolecular C-HÁ Á ÁN, N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds, and intermolecular