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2-Amino-4-(3-methyl-3-p-xylylcyclo­butyl)-1,3-thia­zole

✍ Scribed by Çalı˛skan, Nezihe ;Daĝ, Cemile ;Soylu, Mustafa Serkan ;Cukurovali, Alaaddin ;Koksal, Nurettin Aykut

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
328 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

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The asymmetric unit of the title compound, C 12 H 12 N 2 OS, contains two crystallographically independent molecules. Both molecules are essentially planar and stabilized by intraand intermolecular hydrogen-bonding interactions to form one-dimensional zigzag polymeric chains parallel to the c axis.

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The cyclohexyl ring of the title compound, C 20 H 25 NS 2 , has a chair conformation. The dihedral angle between the thiazole and phenyl rings is 89.70 (2) . The crystal structure involves two weak intramolecular C-HÁ Á ÁS hydrogen-bond contacts.

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In the title compound, C 18 H 23 NS 2 , the bond lengths and angles are unexceptional. The butyl chain is in a fully extended conformation. The dihedral angle between the thiazole and phenyl rings is 87.21 (2) . The crystal structure is stabilized by one weak intramolecular C-HÁ Á ÁS hydrogen bond.

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The molecular structure of (I), with 50% probability displacement ellipsoids.

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